Dichloridotris(2-methyl-1H-imidazole-κN3)cadmium
نویسندگان
چکیده
منابع مشابه
1-Methyl-5-nitro-1H-imidazole
In the title compound, C(4)H(5)N(3)O(2), the nitro group is twisted with respect to the imidazole ring by a dihedral angle of 5.60 (2)°. Weak inter-molecular C-H⋯O and C-H⋯N hydrogen bonding is present in the crystal structure.
متن کامل1-Methyl-4,5-dinitro-1H-imidazole
In the title compound, C(4)H(4)N(4)O(4), the two nitro groups are twisted with respect to the imidazole plane, making dihedral angles of 24.2 (3) and 33.4 (4)°. In the crystal structure, the mol-ecules are linked through non-classical inter-molecular C-H⋯O hydrogen bonds.
متن کاملDichloridotris(2-methyl-1H-imidazole-κN 3)cadmium
In the title compound, [CdCl(2)(C(4)H(6)N(2))(3)], the Cd(II) atom displays a penta-coordinate CdN(3)Cl(2) coordination geometry, being coordinated by an N atom of three 2-methyl-imidazole ligands and two Cl atoms. In the crystal, the mononuclear complexes are linked by N-H⋯Cl hydrogen bonds into a two-dimensional network in the ab plane.
متن کاملBis{1-[(1H-benzotriazol-1-yl)methyl]-2-methyl-1H-imidazole-κN 3}dichloridocobalt(II)
In the title mononuclear complex, [CoCl(2)(C(11)H(11)N(5))(2)], the Co(II) atom is four-coordinated by two ligand N atoms and two Cl atoms in a distorted tetra-hedral geometry. In the crystal, mol-ecules are stacked through π-π inter-actions [centroid-centroid distances = 3.473 (2), 3.807 (3), 3.883 (2) and 3.676 (2) Å], forming a three-dimensional supra-molecular network.
متن کاملCrystal structures of the two salts 2-methyl-1H-imidazol-3-ium nitrate–2-methyl-1H-imidazole (1/1) and 2-methyl-1H-imidazol-3-ium nitrate
The title salts, C4H7N2 (+)·NO3 (-)·C4H6N2, (I), and C4H7N2 (+)·NO3 (-), (II), were obtained from solutions containing 2-methyl-imidazole and nitric acid in different concentrations. In the crystal structure of salt (I), one of the -NH H atoms of the imidazole ring shows half-occupancy, hence only every second mol-ecule is in its cationic form. The nitrate anion in this structure lies on a twof...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2012
ISSN: 1600-5368
DOI: 10.1107/s160053681201104x